1C111Propellants and constituent chemicals for propellants, other than those specified in 1C011, as follows:

a. Propulsive substances:
1. Spherical or spheroidal aluminium powder other than that specified in the Military Goods Controls, in particle size of less than 200 μm and an aluminium content of 97 % by weight or more, if at least 10 % of the total weight is made up of particles of less than 63 μm, according to ISO 2591-1:1988 or national equivalents;
Technical Note:
A particle size of 63 μm (ISO R-565) corresponds to 250 mesh (Tyler) or 230 mesh (ASTM standard E-11).
2. Metal powders, other than that specified in the Military Goods Controls, as follows:
a. Metal powders of zirconium, beryllium or magnesium, or alloys of these metals, if at least 90 % of the total particles by particle volume or weight are made up of particles of less than 60 μm (determined by measurement techniques such as using a sieve, laser diffraction or optical scanning), whether spherical, atomised, spheroidal, flaked or ground, consisting 97 % by weight or more of any of the following:
1. Zirconium;
2. Beryllium; or
3. Magnesium;
Technical Note:
The natural content of hafnium in the zirconium (typically 2 % to 7 %) is counted with the zirconium.
b. Metal powders of either boron or boron alloys with a boron content of 85 % or more by weight, if at least 90 % of the total particles by particle volume or weight are made up of particles of less than 60 μm (determined by measurement techniques such as using a sieve, laser diffraction or optical scanning), whether spherical, atomised, spheroidal, flaked or ground;
Note:
1C111a.2.a. and 1C111a.2.b. controls powder mixtures with a multimodal particle distribution (e.g. mixtures of different grain sizes) if one or more modes are controlled.
3. Oxidiser substances usable in liquid propellant rocket engines as follows:
a. Dinitrogen trioxide (CAS 10544-73-7);
b. Nitrogen dioxide (CAS 10102-44-0)/dinitrogen tetroxide (CAS 10544-72-6);
c. Dinitrogen pentoxide (CAS 10102-03-1);
d. Mixed Oxides of Nitrogen (MON);
Technical Note:
Mixed Oxides of Nitrogen (MON) are solutions of Nitric Oxide (NO) in Dinitrogen Tetroxide/Nitrogen Dioxide (N2O4/NO2 ) that can be used in missile systems. There are a range of compositions that can be denoted as MONi or MONij, where i and j are integers representing the percentage of Nitric Oxide in the mixture (e.g., MON3 contains 3 % Nitric Oxide, MON25 25 % Nitric Oxide. An upper limit is MON40, 40 % by weight).
e. SEE MILITARY GOODS CONTROLS FOR Inhibited Red Fuming Nitric Acid (IRFNA);
f. SEE MILITARY GOODS CONTROLS AND 1C238 FOR compounds composed of fluorine and one or more of other halogens, oxygen or nitrogen.
4. Hydrazine derivatives as follows:
N.B. SEE ALSO MILITARY GOODS CONTROLS.
a. Trimethylhydrazine (CAS 1741-01-1);
b. Tetramethylhydrazine (CAS 6415-12-9);
c. N,N-Diallylhydrazine (CAS 5164-11-4);
d. Allylhydrazine (CAS 7422-78-8);
e. Ethylene dihydrazine (CAS 6068-98-0);
f. Monomethylhydrazine dinitrate;
g. Unsymmetrical dimethylhydrazine nitrate;
h. Hydrazinium azide (CAS 14546-44-2);
i. 1,1-Dimethylhydrazinium azide (CAS 227955-52-4) / 1,2-Dimethylhydrazinium azide (CAS 299177-50-7);
j. Hydrazinium dinitrate (CAS 13464-98-7);
k. Diimido oxalic acid dihydrazine (CAS 3457-37-2);
l. 2-hydroxyethylhydrazine nitrate (HEHN);
m. See Military Goods Controls for Hydrazinium perchlorate;
n. Hydrazinium diperchlorate (CAS 13812-39-0);
o. Methylhydrazine nitrate (MHN) (CAS 29674-96-2);
p. 1,1-Diethylhydrazine nitrate (DEHN) / 1,2-Diethylhydrazine nitrate (DEHN) (CAS 363453-17-2);
q. 3,6-Dihydrazino tetrazine nitrate (1,4-dihydrazine nitrate) (DHTN);
5. High energy density materials, other than that specified in the Military Goods Controls, usable in 'missiles' or unmanned aerial vehicles specified in 9A012 or 9A112.a.;
a. Mixed fuel that incorporate both solid and liquid fuels, such as boron slurry, having a mass-based energy density of 40 × 106 J/kg or greater;
b. Other high energy density fuels and fuel additives (e.g., cubane, ionic solutions, JP-10) having a volume-based energy density of 37,5 × 109 J/m3 or greater, measured at 20 °C and one atmosphere (101,325 kPa) pressure;
Note:
1C111.a.5.b. does not control fossil refined fuels and biofuels produced from vegetables, including fuels for engines certified for use in civil aviation, unless specially formulated for 'missiles' or unmanned aerial vehicles specified in 9A012 or 9A112.a..
Technical Note:
In 1C111.a.5. 'missile' means complete rocket systems and unmanned aerial vehicle systems capable of a range exceeding 300 km.
6. Hydrazine replacement fuels as follows:
a. 2-Dimethylaminoethylazide (DMAZ) (CAS 86147-04-8);
b. Polymeric substances:
1. Carboxy-terminated polybutadiene (including carboxyl-terminated polybutadiene) (CTPB);
2. Hydroxy-terminated polybutadiene (including hydroxyl-terminated polybutadiene) (HTPB) (CAS 69102-90-5), other than that specified in the Military Goods Controls;
3. Polybutadiene-acrylic acid (PBAA);
4. Polybutadiene-acrylic acid-acrylonitrile (PBAN) (CAS 25265-19-4 / CAS 68891-50-9);
5. Polytetrahydrofuran polyethylene glycol (TPEG);
Technical Note:
Polytetrahydrofuran polyethylene glycol (TPEG) is a block co-polymer of poly 1,4-Butanediol (CAS 110-63-4) and polyethylene glycol (PEG) (CAS 25322-68-3).
6. SEE MILITARY GOODS CONTROLS FOR polyglycidyl nitrate (PGN or poly-GLYN) (CAS 27814-48- 8).
c. Other propellant additives and agents:
1. SEE MILITARY GOODS CONTROLS FOR Carboranes, decaboranes, pentaboranes and derivatives thereof;
2. Triethylene glycol dinitrate (TEGDN) (CAS 111-22-8);
3. 2-Nitrodiphenylamine (CAS 119-75-5);
4. SEE MILITARY GOODS CONTROLS FOR trimethylolethane trinitrate (TMETN) (CAS 3032-55-1);
5. Diethylene glycol dinitrate (DEGDN) (CAS 693-21-0);
6. Ferrocene derivatives as follows:
a. SEE MILITARY GOODS CONTROLS FOR catocene (CAS 37206-42-1);
b. SEE MILITARY GOODS CONTROLS FOR Ethyl ferrocene (CAS 1273-89-8);
c. SEE MILITARY GOODS CONTROLS FOR n-Propyl ferrocene (CAS 1273-92-3)/iso-propyl ferrocene (CAS 12126-81-7);
d. SEE MILITARY GOODS CONTROLS FOR n-butyl ferrocene (CAS 31904-29-7);
e. SEE MILITARY GOODS CONTROLS FOR Pentyl ferrocene (CAS 1274-00-6);
f. SEE MILITARY GOODS CONTROLS FOR Dicyclopentyl ferrocene (CAS 125861-17-8);
g. SEE MILITARY GOODS CONTROLS FOR Dicyclohexyl ferrocene;
h. SEE MILITARY GOODS CONTROLS FOR Diethyl ferrocene (CAS 1273-97-8);
i. SEE MILITARY GOODS CONTROLS FOR Dipropyl ferrocene;
j. SEE MILITARY GOODS CONTROLS FOR Dibutyl ferrocene (CAS 1274-08-4);
k. SEE MILITARY GOODS CONTROLS FOR Dihexyl ferrocene (CAS 93894-59-8);
l. SEE MILITARY GOODS CONTROLS FOR Acetyl ferrocene (CAS 1271-55-2) / 1,1'-diacetyl ferrocene (CAS 1273-94-5);
m. SEE MILITARY GOODS CONTROLS FOR Ferrocene carboxylic acid (CAS 1271-42-7) / 1,1'-Ferrocenedicarboxylic acid (CAS 1293-87-4) ;
n. SEE MILITARY GOODS CONTROLS FOR butacene (CAS 125856-62-4);
o. Other ferrocene derivatives usable as rocket propellant burning rate modifiers, other than those specified in the Military Goods Controls.
Note:
1C111.c.6.o. does not control ferrocene derivatives that contain a six carbon aromatic functional group attached to the ferrocene molecule.
7. 4,5-Diazidomethyl-2-methyl-1,2,3-triazole (iso-DAMTR), other than that specified in the Military Goods Controls.
d. 'Gel propellants', other than that specified in the Military Goods Controls, specifically formulated for use in 'missiles'.
Technical Notes:
1. In 1C111.d. a 'gel propellant' is a fuel or oxidiser formulation using a gellant such as silicates, kaolin (clay), carbon or any polymeric gellant.
2. In 1C111.d. a 'missile' means complete rocket systems and unmanned aerial vehicle systems capable of a range exceeding 300 km.
Note:
For propellants and constituent chemicals for propellants not specified in 1C111, see the Military Goods Controls.